(S)-(–)-Methyl 2-(p-tolylsulfonyloxy)propanoate
نویسندگان
چکیده
منابع مشابه
(S)-(–)-Methyl 2-(p-tolylsulfonyloxy)propanoate
In the title compound, C(11)H(14)O(5)S, there is an intra-molecular C-H⋯O hydrogen bond, for which the C-C-S-O torsion angle involving the acceptor and donor atoms is 2.4 (4)°. The dihedral angle between the benzene ring and the methoxy-carbonyl plane is 52.7 (4)°. In the crystal structure, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds, forming a mol-ecular chain along the b axis.
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The title compound, [Fe(C(5)H(5))(C(19)H(16)O(2)P)], obtained serendipitously during recrystallization of 1-hydroxy-benzotriazolyl (S(p))-2-(diphenyl-phosphino)ferrocene-1-carboxyl-ate from meth-anol, crystallizes in the chiral space group P2(1)2(1)2(1). Its crystal structure not only confirms the anti-cipated absolute configuration but also establishes a rather regular geometry for the ferroce...
متن کاملMethyl 2-(p-toluenesulfonamido)benzoate
The title compound, C(15)H(15)NO(4)S, was prepared by simple condensation of methyl 2-amino-benzoate and 4-methyl-benzene-sulfonyl chloride. The dihedral angle between the benzene rings is 84.36 (6)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen-bonding inter-action involving the carbonyl group as acceptor, generating an S(6) graph-set motif.
متن کامل2-Bromo-2-methyl-N-p-tolylpropanamide
In the title mol-ecule, C(11)H(14)BrNO, there is twist between the mean plane of the amide group and the benzene ring [C(=O)-N-C C torsion angle = -31.2 (5)°]. In the crystal, inter-molecular N-H⋯O and weak C-H⋯O hydrogen bonds link mol-ecules into chains along [100]. The methyl group H atoms are disordered over two sets of sites with equal occupancy.
متن کاملN-(4-Methyl-2-pyridyl)-p-toluidine
In the title compound, C(13)H(14)N(2), the dihedral angle between the aromatic rings is 48.1 (1)° and the bridging C-N-C bond angle is 127.24 (12)°. In the crystal, intermolecular N-H⋯N hydrogen bonding about a center of inversion generates a hydrogen-bonded dimer.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808010064